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Chemical Application

Chemical Application

Proper chemical selection is the basis for successful cleaning, with access to a line of specialized in-house chemistry, we can seamlessly integrate the optimized set of chemistry with the correct cleaning methodology for the best results.

With endless types of chemistry in the marketplace, we understand that determining the optimized chemistry for each scope of work can be overwhelming. Using our experience, we will select a strategic set of chemistry that will best suit your needs. Our chemical cleaning arsenal includes:

  • Degreasing
  • Acid Pickling
  • Passivation
  • Heavy Hydrocarbon Removal: Solvent Based
  • Heavy Hydrocarbon Removal: Water Based
  • Decontamination
  • NORMs Removal
  • Chlorination

Many of these chemical applications can be applied in series to meet multiple requirements. Some examples include:

Initial degrease to maximize pickling fluid contact, followed by a pickle to remove rust and passivation to protect surfaces before equipment is placed back into service.

Initial removal of heavy sludge followed by removal of contaminants such as LELs & H2S in preparation for vessel entry and inspection.

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CASE STUDY

Degassing and Decontamination of a Crude Unit
This was the first vapour-phase application where the entire crude unit was to be degassed and decontaminated simultaneously. Previously, the client had broken down the unit into separate individual stages with each degassing operation taking place over 48-hours.

Degreasing

Degreasing uses alkaline solution to remove organic matter from surfaces.  The caustic mixture normally contains other additives such as sodium meta-silicate, sodium carbonate, and surfactants and antifoaming agents to increase degreasing efficiency.

For applications where metallurgy is sensitive to chloride concentrations our specialty chemical FQE Degreaser-ACMO is recommended.  This is a special blend that contains emulsifier that can phase separate upon completion of decreasing.  This will concentrate oils and grease before disposal to minimize disposal costs.

Acid Pickling

Mineral Acids:  Such as hydrochloric acid, sulfamic acid, sulfuric acid, etc. are the conventional method for pickling to remove millscale and rust. These acids have varying degrees of aggressiveness and is often economical.

Chelating Agents:  Are chemistries that can bind metal ions to its molecule.  While these are not as cost-effective as mineral acids, they are inherently safer for projects where safety is a major concern.

Passivation

To protect a newly pickled surface before the equipment/piping is put back into service passivation forms a layer of gamma hematite on contact surfaces by using oxidative chemistries.  This layer facilitates rust reformation after the effort of acid pickling has been conducted.

Heavy Hydrocarbon Removal: Solvent Based Flushing

Limited effectiveness has been reported for standard degreasing chemistry in extreme cases where hydrocarbon sludges contain asphaltenes and other high molecular weight organic matter. In these scenarios, FQE offers house blends of chemistry that can quickly dissolve these sticky situations.

FQE Solvent H is a concentrated liquid asphaltene dispersant created from benzene free aromatic petroleum solvents containing selected dispersants, penetrants, wetting and anti-static agents.  It can quickly dissolve solid hydrocarbon deposits found in equipment such as vacuum tower bottoms.  As an added advantage, FQE Solvent H has also found its use in applications where the sludge is to be recycled into process streams to minimize waste generation and maximize product recovery.

Removing Solid Asphalt Via Vapour Phase

 

This experiment was set up to determine the efficiency of asphaltene dissolution using FQE Solvent-H versus two industry alternatives and water. As evidenced in the experiment, the soluble asphaltene was completely dissolved with vapor phase application of FQE Solvent-H. The alternatives tested essentially yielded the same results as using water (steam).

At the end of an hour, when only insoluble coke remained in the FQE beaker, a spatula was used to easily remove particulates from the beaker wall. FQE Solvent-H condensate was then transferred with the spatula to the other three beakers. The powerful active ingredients of FQE Solvent-H, in condensate, was able to solubilize the deposits in the remaining beakers.

In essence, the experiment mimics decontamination of vertical vessels using a vapor phase cleaning technique. The asphalt along the side of the beakers represent heavy fouling of vessels and process equipment, easily addressed by FQE Solvent-H.

Dissolving Crystalline Asphalt

Heavy Hydrocarbon Removal: Water Based Flushing

As an alternative, FQE Solvent ME is water-based micro emulsion cleaner that has asphaltene, and high mole weight waxes dissolving power.  As it is water-based, it is inherently safe chemistry which can be quickly removed with a water rinse before equipment is placed back into service.

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CASE STUDY

SAGD ASSET INTEGRITY: THE RACE FOR PRESERVATION

With system integrity insurance hanging in the balance for a SAGD Facility, bitumen emulsion removal and preservation was conducted on major vessels, equipment, and piping.

Decontamination

As a routine part of maintenance, many vessel and tanks require vessel entry for inspection and mechanical cleaning. These entries require safety watches and supplied air as the atmospheres can be contaminated with high concentrations of ammonia, pyrophoric ions, LELs and H2S. In order to create safer working environments, FQE can decontaminate these confined spaces with a blend of many of our house chemistries including FQE LEL-V, FQE LEL-V Eco, FQE H2SFQE Pyrophoric, and FQE Ammonia Odor.

Chlorination

For lines and vessels that are placed in service for potable water, microorganisms must be kept at an acceptable level. This is accomplished through the use of chemicals such as sodium hypochlorite and sodium thiosulfate.

NORMs Removal

When NORMs (Naturally occurring radioactive materials) concentrations in vessels and tanks reach an unacceptable level they present a health hazard to personnel who are exposed.  FourQuest has a patented set of chemistry (FQE NORM-Clear and FQE NORM-Precip) that first exacts the NORM by dissolving the deposits followed by the removal of the dissolved salts to obtain radioactive free wastewater.

NORM Decontamination
CONTAMINANT

NORM DECONTAMINATION

FQE NORM-Clear is a water soluble product designed to completely remove NORM (normally occurring radioactive material) contamination from vessels, tanks, or process pipework.

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Looking for more information on this service line? Use the form to the right to be contacted by a member of our Technical Sales Team. For additional information like brochures and case histories, visit our Resource Library

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